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Deanship of Graduate Studies
Document Details
Document Type
:
Thesis
Document Title
:
Kinetics and Mechanism of Formation of Silver Nanoparticles in Aqueous Medium in Presence of some Active Surfactants
حركية وميكانيكية تكوين جسيمات الفضة النانونية في الوسط المائي في وجود بعض السطوح النشطة
Subject
:
Faculty of Sciences > Chemistry department
Document Language
:
Arabic
Abstract
:
The kinetics and mechanism of the formation of silver nanoparticles (AgNPs) by reduction with ribose and glucose were studied spectrophotometrically under pseudo-first-order condition in aqueous micellar media over 45 – 60 oC and variety of [OH-] range. The rate of reaction increases with increasing of the [OH-]. Cetyltrimethylammoniuom bromide (CTAB), sodium dodecyl sulphate (SDS) were used as stabilizer for the formed silver nanoparticles. The Effect of [Ag+], [sugar], [NaOH] and [micelles] on the reaction rate was investigated. The proposed mechanism is derived which is consistent with the experimental rate law. Thermodynamic activation parameters were calculated. The particle size of silver sols was characterized by the transmission electron microscopic (TEM), SEM and physio-chemical and spectroscopic methods.
Supervisor
:
Dr. Iqbal M. I. Ismail
Thesis Type
:
Master Thesis
Publishing Year
:
1435 AH
2014 AD
Co-Supervisor
:
Dr. Hassan A. Ewais
Added Date
:
Monday, May 5, 2014
Researchers
Researcher Name (Arabic)
Researcher Name (English)
Researcher Type
Dr Grade
Email
خلف حسن الفاهمي
Al-Fahmi, Khalaf Hassan
Researcher
Master
Files
File Name
Type
Description
36883.pdf
pdf
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