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Document Details
Document Type
:
Article In Journal
Document Title
:
Negative Solvatochromism of Ferrocenyl Methine Dyes
تأثير مذيب سلبي لأصباغ الميثان المشتقة من الفروسين
Subject
:
Chemistry
Document Language
:
English
Abstract
:
A novel solvatochromic ferrocenyl methine dyes has been synthesized by condensation of ferrocen-3-caboxaldehyde with active methylene compounds under Knoevengel conditions and characterized by UV-vis in a range of solvents. Compound 1a has a red shift in ?-?* and a blue shift increases with solvent polarity in the MLCT (M?A) while 1b-1d variation of red as well as blue shifts from both states. No d-d transition is observed in these compounds. These shifts are interpreted by different dipole moments in the ground and excited state as well as solvent interaction between solute/solvent and H-bonding with the acceptor.
ISSN
:
1319-1012
Journal Name
:
Journal of King Abdulaziz University
Volume
:
21
Issue Number
:
1
Publishing Year
:
2009 AH
2009 AD
Article Type
:
Article
Added Date
:
Sunday, January 31, 2010
Researchers
Researcher Name (Arabic)
Researcher Name (English)
Researcher Type
Dr Grade
Email
Abdullah محمد عسيري
Asiri, عبدالله Mohamed
Researcher
Doctorate
aasiri2@kau.edu.sa
محمد سعيد العمودي
Al-Amoudi, Muhammed S
Researcher
Doctorate
Files
File Name
Type
Description
24957.pdf
pdf
Abstract
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